Dispersed fluorescence spectra of the CCl2 ÖX̃ vibronic bands
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چکیده
Laser excited, dispersed fluorescence spectra have been recorded for a number of bands of the ÖX~ electronic transition of CCl2 . Analysis of the data yields well defined values for the harmonic and anharmonic constants for the symmetric ground state vibrations. Additional lines are observed at red shifts 5000 cm 1 from the origin, which are not assignable in terms of the known X~ and à state structure. A possible explanation for these transitions would be perturbations of the singlet X~ structure by the low-lying triplet ã state.
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تاریخ انتشار 2003